{"id":494,"date":"2024-06-25T12:15:01","date_gmt":"2024-06-25T10:15:01","guid":{"rendered":"https:\/\/shine.chem.polimi.it\/?page_id=494"},"modified":"2024-06-25T12:15:02","modified_gmt":"2024-06-25T10:15:02","slug":"strategies-and-objectives","status":"publish","type":"page","link":"https:\/\/shine.chem.polimi.it\/?page_id=494","title":{"rendered":"Strategies and objectives"},"content":{"rendered":"\n<p><strong>WP1: Design and synthesis of cations and HPs<\/strong><\/p>\n\n\n\n<p>Tailored XB-donors cations are the cornerstones of project\u2019s objectives and will be synthesized, characterized and applied for the construction of HPs within WP1. Crystallization experiments will allow to obtain single-crystals for structure determination in WP3.<\/p>\n\n\n\n<p><strong>WP2: Computational modelling<\/strong><\/p>\n\n\n\n<p>Computational studies in correlation with experimental results will be used for providing correct information on cation steric and electronic features and their effect on HPs structure and properties.<\/p>\n\n\n\n<p><strong>WP3: Structural characterization via X-Ray diffraction and <\/strong><strong>ssNMR<\/strong><\/p>\n\n\n\n<p>This WP will be devoted to the structural characterization of materials obtained in WP1 using two main techniques: i) X-Ray<\/p>\n\n\n\n<p>diffraction and ii) ssNMR spectroscopy.<\/p>\n\n\n\n<p><strong>WP4: <\/strong><strong>Photophysical<\/strong><strong> <\/strong><strong>investigation<\/strong><\/p>\n\n\n\n<p>Trapping processes of charges and excitons will be investigated&nbsp; and&nbsp; cooperative phenomena occurring in highly ordered structures will be highlighted. Optical properties of newly synthesized LDHPs will be studied with a wide set of complementary spectroscopic&nbsp; techniques allowing to highlight and interpret the effects of XB on the structure of the developed materials<strong>.<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>WP1: Design and synthesis of cations and HPs Tailored XB-donors cations are the cornerstones of project\u2019s objectives and will be synthesized, characterized and applied for the construction of HPs within WP1. Crystallization experiments will allow to obtain single-crystals for structure determination in WP3. WP2: Computational modelling Computational studies in correlation with experimental results will be&hellip;<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-494","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/pages\/494","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=494"}],"version-history":[{"count":1,"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/pages\/494\/revisions"}],"predecessor-version":[{"id":495,"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=\/wp\/v2\/pages\/494\/revisions\/495"}],"wp:attachment":[{"href":"https:\/\/shine.chem.polimi.it\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=494"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}